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Creators/Authors contains: "Sar, Dinabandhu"

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  1. Herein, we report the dicarbofunctionalization of enol silyl ethersviaan Fe-catalyzed decoupled cross-coupling of (fluoro)alkyl halides, and enol silyl ethers. 
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  2. An iron-catalyzed regioselective dicarbofunctionalization of electron-rich alkenes is described. In particular, aryl- and alkyl vinyl ethers are used as effective linchpins to couple alkyl or (fluoro)alkyl halides and sp 2 -hybridized Grignard nucleophiles. Preliminary results demonstrate the ability to engage thioethers as linchpins and control enantioselectivity in these transformations, an area which is largely unexplored in iron-catalyzed three-component cross-coupling reactions. 
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